반응 #2383774

반응 방정식

1,4-benzoquinone

1,2-bis(dibromomethyl)benzene

sodium iodide

→

1,4-anthraquinone

수율 47.0%

용매

dimethylformamide

반응 조건

후처리

1. 1
   기타After the exothermic reaction
2. 2
   기타the formed crystals were separated by filtration
3. 3
   세척washed with methanol and water and 23 g (the yield: 47%) of light yellow needle crystals of 1,4-anthraquinone
4. 4
   기타were obtained

실험 절차

In an atmosphere of argon, 60 g (550 mmole) of 1,4-benzoquinone, 100 g (240 mmole) of 1,2-bis(dibromomethyl)benzene and 235 g (1.6 mole) of sodium iodide were dissolved into 850 ml of dry dimethylformamide. After the exothermic reaction was completed, the reaction solution was heated to 70° C. and stirred for 8 hours. After the reaction was completed, the formed crystals were separated by filtration and washed with methanol and water and 23 g (the yield: 47%) of light yellow needle crystals of 1,4-anthraquinone were obtained.

출처