반응 #219202

반응 방정식

acrylate

isocyanate

dibutyltin laurate

isocyanate

→

Urethane Acrylate

용매

반응 조건

후처리

1. 1
   기타air was purged through the reaction mixture
2. 2
   workup.ADDITIONwas added
3. 3
   온도the temperature of the kettle was increased to 77° C
4. 4
   기타a sample was withdrawn for analysis

실험 절차

A quantity of 0.1 moles of isocyanate terminated prepolymer and 0.1 ml of dibutyltin laurate were charged to a 500 ml glass kettle. The mixture was heated at 70° C. and air was purged through the reaction mixture and a solution of diol (0.05 moles) was added dropwise while the mixture was stirred at 200 RPM. After a two hour reaction, hydroyethyl acrylate (0.1 moles) was added to cap the residual isocyanate and the temperature of the kettle was increased to 77° C. After another two hours, a sample was withdrawn for analysis. The remainder was transferred to a bottle and stored in darkness.

출처