반응 #2161238

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triphenylsulfonium chloride

sodium 1,1,3,3,3-pentafluoro-2-benzoyloxy-propane-1-sulfonate

→

triphenylsulfonium 1,1,3,3,3-pentafluoro-2-benzoyloxypropane-1-sulfonate

수율 75.0%

용매

dichloromethane

반응 조건

후처리

1. 1
   기타synthesized in Synthesis Example 9
2. 2
   기타The organic layer was separated
3. 3
   세척washed with 50 g of water three times
4. 4
   농축The organic layer was concentrated
5. 5
   workup.ADDITION25 g of diethyl ether was added to the residue for crystallization
6. 6
   여과The crystals were filtered
7. 7
   기타dried
8. 8
   기타obtaining the target compound

실험 절차

To 50 g of dichloromethane were added an amount (corresponding to 0.011 mole) of the triphenylsulfonium chloride aqueous solution of Synthesis Example 1 and 3.6 g (0.01 mole) of sodium 1,1,3,3,3-pentafluoro-2-benzoyloxy-propane-1-sulfonate synthesized in Synthesis Example 9, followed by stirring. The organic layer was separated and washed with 50 g of water three times. The organic layer was concentrated and 25 g of diethyl ether was added to the residue for crystallization. The crystals were filtered and dried, obtaining the target compound. White crystals, 4.5 g (yield 75%).

출처