반응 #215693

ord-76ffd24e304642158af2cc014d8e9207

반응 방정식

O=C(O)Cc1ccc(Br)cc1
4-bromophenylacetic acid
O=C1CCc2cc(Br)ccc2C1
6-bromo-2-tetralone
O=C(Cl)C(=O)Cl
Oxalyl chloride
O=C(Cl)Cc1ccc(Br)cc1
4-bromo-phenylacetyl chloride

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

The synthesis of 6-bromo-2-tetralone is accomplished by dissolving 4-bromophenylacetic acid in methylene chloride and dimethyl formamide, under nitrogen. Oxalyl chloride is added and the mixture is stirred under a positive nitrogen atmosphere to produce the 4-bromo-phenylacetyl chloride, at a yield which typically is better than 99%.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05464762uspto-grants-1995_11