반응 #215328

ord-556bbc3a328e454ab039bc372f2aeabf

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

Prod.: (many methods) e.g. from Myrcene, via Myrcene dihydrochloride to Dichloro di-methyloctene. This is converted to Chloro di-hydrogeranyl acetate (and-neryl acetate) with Sodium Acetate in Benzene in presence of Triethylamine. The acetates are saponified with Calcium hydroxide to yield Hydroxycitronellol, from which the aldehyde is prepared by oxidation.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04258727uspto-grants-1981_03