반응 #215042

반응 방정식

mesityl oxide

t-amyl hydroperoxide

→

2-METHYL-2-(t-AMYLPEROXY)-4-PENTANONE

용매

Hexane

반응 조건

후처리

1. 1
   기타the ion-exchange resin separated by filtration
2. 2
   세척The filtrate was washed with sodium bisulfite solution and with water
3. 3
   건조the organic layer dried over anhydrous magnesium sulfate
4. 4
   기타The hexane solvent was removed under reduced pressure

실험 절차

A reaction mixture of 11.8 g (0.12 mole) of mesityl oxide, 30 g of Amberlyst 15® sulfonic acid type ion-exchange resin, and 15.6 g (0.15 mole) of 89% t-amyl hydroperoxide was stirred at 25°-30° C. for 20 hours and at 40° C. for 1 hour. Hexane was added and the ion-exchange resin separated by filtration. The filtrate was washed with sodium bisulfite solution and with water and the organic layer dried over anhydrous magnesium sulfate. The hexane solvent was removed under reduced pressure and the 11.7 g of recovered product identified by its infrared spectrum.

출처