반응 #214839

반응 방정식

diphenyliodonium chloride

fluoroboric acid

phosphorous acid

diphenyliodonium bisulfate

→

diphenyliodonium fluoroborate

용매

water

반응 조건

후처리

1. 1
   기타is prepared by the addition of 60° C. of an aqueous solution
2. 2
   workup.ADDITIONcontaining 29.2 g
3. 3
   기타The silver halide that precipitates
4. 4
   여과is filtered off
5. 5
   농축the filtrate concentrated

실험 절차

The aromatic iodonium complex salts may be prepared by metathesis of corresponding aromatic iodonium simple salts (such as, for example, the diphenyliodonium bisulfate) in accordance with the teachings of Beringer, et al., J. Am. Chem. Soc. 81, 342 (1959). Thus, for examples, the complex salt diphenyliodonium tetrafluoroborate is prepared by the addition of 60° C. of an aqueous solution containing 29.2 g. (150 millimoles) silver fluoroborate, 2 g. fluoroboric acid, and 0.5 g. phosphorous acid in about 30 ml. of water to a solution of 44 g. (139 millimoles) of diphenyliodonium chloride. The silver halide that precipitates is filtered off and the filtrate concentrated to yield diphenyliodonium fluoroborate which may be purified by recrystallization.

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