반응 #2139032

ord-cb84155c1c364e4d85c4f07e6db34637

반응 방정식

C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O
L-rhamnose
CCCCN
n-butylamine
O=C=NCCCl
2-chloroethyl isocyanate
CCCCN(C(=O)NCCCl)C1O[C@@H](C)[C@H](O)[C@@H](O)[C@H]1O
1-(2-chloroethyl)-3-n-butyl-3-L-rhamnopyranosylurea
수율 64.3%

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

3.3 g of L-rhamnose, 1.8 g of n-butylamine and 2.5 g of 2-chloroethyl isocyanate are treated in the same manner as described in Example 5-(1). 4.2 g of 1-(2-chloroethyl)-3-n-butyl-3-L-rhamnopyranosylurea are thereby obtained as colorless caramel.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04182757uspto-grants-1980_01