반응 #2122506

반응 방정식

Aluminum chloride

cyclohexyl chloride

→

tricyclohexylbenzene

수율 50.7%

용매

benzene

반응 조건

후처리

1. 1
   workup.ADDITIONAfter the dropwise addition
2. 2
   workup.STIRRINGthe resultant was stirred at room temperature for 5 hours
3. 3
   기타the obtained reaction solution
4. 4
   추출The organic layer was extracted
5. 5
   기타the obtained organic layer was removed by distillation at 40° C. under reduced pressure
6. 6
   기타The resultant was further removed by distillation at 170° C. under reduced pressure
7. 7
   온도cooled to room temperature
8. 8
   workup.ADDITION50 ml of acetone was added
9. 9
   기타recrystallization
10. 10
    기타The precipitated crystals were collected
11. 11
    여과through filtering

실험 절차

Aluminum chloride (6.38 g) was added to 20.0 g of benzene, followed by stirring under cooling at 3° C., and 40.4 g of cyclohexyl chloride was slowly added dropwise thereto. After the dropwise addition, the resultant was stirred at room temperature for 5 hours, and the obtained reaction solution was added to ice water. The organic layer was extracted by using ethyl acetate, and the obtained organic layer was removed by distillation at 40° C. under reduced pressure. The resultant was further removed by distillation at 170° C. under reduced pressure and then cooled to room temperature, and 50 ml of acetone was added thereto to cause recrystallization. The precipitated crystals were collected through filtering, thereby obtaining 14 g of tricyclohexylbenzene.

출처