반응 #2025160

ord-dc99eeb138404de8bd114910c5b87d2f

반응 방정식

CC1(C)OB(c2cnc3ccccc3c2)OC1(C)C
CC1(C)OB(c2cnc3ccccc
Brc1ccc2cc[nH]c2c1
Brc1ccc2cc[nH]c2c1
→
c1ccc2ncc(-c3ccc4cc[nH]c4c3)cc2c1
c1ccc2ncc(-c3ccc4cc[
수율 76.0%

반응물

CC1(C)OB(c2cnc3ccccc3c2)OC1(C)C
CC1(C)OB(c2cnc3ccccc3c2)OC1(C)
Brc1ccc2cc[nH]c2c1
Brc1ccc2cc[nH]c2c1

시약

CC(C)(C)c1ccc(-c2ccc(C(C)(C)C)cc2)cc1
CC(C)(C)c1ccc(-c2ccc(C(C)(C)C)
[Pd].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
[Pd].c1ccc(P(c2ccccc2)c2ccccc2
O=C([O-])[O-].[Na+].[Na+]
O=C([O-])[O-].[Na+].[Na+]

용매

COCCOC
COCCOC
COCCOC
COCCOC
O
water

반응 조건

온도
85°CELSIUS

후처리

  1. 1
    workup.STIRRING

출처

DOI: 10.1039/c5sc04751jPd_CN_Coupling_Informer_Library