반응 #2006421

반응 방정식

olefins

4(3-Phenylpropenyl)-benzoic Acid 4-(3-Phenyl-2-propenyl)-benzoic Acid

→

55

4-(3-Phenylpropyl)-benzoic Acid

용매

methanol

반응 조건

후처리

1. 1
   workup.STIRRINGThe mixture was stirred for 2 hours at room temperature
2. 2
   여과filtered through Celite
3. 3
   기타evaporated

실험 절차

A mixture of regioisomeric olefins 54 (100 mg, 0.42 mmol) and Pd 10% on C (10 mg) in methanol (4 mL) was vigorously stirred under H2 atmosphere (14 psi). The mixture was stirred for 2 hours at room temperature, filtered through Celite and evaporated to afford 55 as an oil. Flash chromatography of the residue gave 55 (88 mg, 88%).

출처