반응 #1994249

반응 방정식

toluene

toluene

maleic anhydride

toluene

hexamethyldisilazane

toluene

3-aminopropyl triethoxysilane

→

N-(3-propyl triethoxysilyl)maleimide

반응 조건

후처리

1. 1
   workup.ADDITIONare added
2. 2
   여과before being filtered
3. 3
   기타isolated by distillation

실험 절차

N-(3-propyl triethoxysilyl)maleimide (PSM) is prepared by the addition of 100 mL of a 2.33 molar saturated anhydrous toluene solution of maleic anhydride (22.85 g of anhydride, 0.233 mol) to a one liter flask containing 100 mL of dry toluene and then, under nitrogen, slowly dripping in a solution of 3-aminopropyl triethoxysilane (51.6 g, 54.8 mL, 0.233 mol) dissolved in 100 mL of dry toluene over a 15 minute period. After stirring 2 hours, anhydrous zinc chloride (10 g, 73.3 mmol) and hexamethyldisilazane (HMDS) (47.0 g, 60.7 mL, 0.291 mol) dissolved in 100 mL of dry toluene are added. The solution is heated to 80° C. for 18 hrs with stifling before being filtered and isolated by distillation.

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