반응 #1985935

반응 방정식

NaNO2

carbon black

Sulfanilic acid

DBPA

→

4-Sulfobenzenediazonium hydroxide

용매

water

반응 조건

후처리

1. 1
   온도with warming
2. 2
   온도to cool

실험 절차

Sulfanilic acid (43 g) was dissolved in 2 L of water with warming. The solution was mixed with 200 g of a carbon black having a surface area of 230 m2 /g and a DBPA of 70 ml/100 g and allowed to cool. An aqueous solution of 20.5 g NaNO2 was added slowly and the resulting dispersion was stirred for one hour. 4-Sulfobenzenediazonium hydroxide inner salt was formed in situ, which reacted with the carbon black. The dispersion was filtered through a Whatman #41 filter, and the product was dried in an oven at 70° C. The product has attached p--C6H4SO3- groups.

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