반응 #1929032

반응 방정식

sodium dichromate dihydrate

ether

1-bromo-2-dodecanol

→

1-bromo-2-dodecanone

수율 80.0%

용매

water

sulfuric acid

acetone

반응 조건

후처리

1. 1
   기타A solution obtained in advance
2. 2
   workup.ADDITIONwas dropped
3. 3
   기타the solvent was removed
4. 4
   기타As a result, a white solid was obtained

실험 절차

In a 1000 ml eggplant-shaped flask, 14 g of 1-bromo-2-dodecanol was dissolved in 110 ml of acetone. A solution obtained in advance by dissolving 35 g of sodium dichromate dihydrate in 150 ml of distilled water and 25 ml of sulfuric acid was dropped thereto. These substances were stirred at room temperature for 1.5 hours, and then 250 ml of ether was added thereto. The resultant substance was dehydrated, and the solvent was removed. As a result, a white solid was obtained. The yield was 80%.

출처