반응 #1909798

반응 방정식

vinylene carbonate

benzenethiol

triethylamine

→

4-phenylsulfanyl-[1,3]dioxolan-2-one

용매

tetrahydrofuran

반응 조건

후처리

1. 1
   온도The mixture was refluxed under an argon atmosphere for 4 hours
2. 2
   기타the solvent was removed through distillation under reduced pressure
3. 3
   기타purified

실험 절차

In 70 mL of tetrahydrofuran (THF), 3 g of vinylene carbonate and 5.1 g of benzenethiol were dissolved, and then 4.7 g of triethylamine was added. The mixture was refluxed under an argon atmosphere for 4 hours. When the reaction was finished, the solvent was removed through distillation under reduced pressure, and the resulting material was subjected to the column chromatography on silica gel (eluted with 20% hexane/ethylacetate) and purified to obtain a target product, 4-phenylsulfanyl-[1,3]dioxolan-2-one.

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