반응 #1824305

반응 방정식

trimethoxysilane

allyl glycidyl ether

trimethoxysilane

→

3-glycidoxypropyltrimethoxysilane

수율 86.0%

반응 조건

후처리

1. 1
   기타The exotherm of the reaction was controlled with an ice bath
2. 2
   온도to maintain the temperature at 90°-95° C
3. 3
   workup.ADDITIONThe addition
4. 4
   온도temperature was maintained at 90°-95° C. for another hour

실험 절차

The apparatus of Example B was charged with 136.8 gm (1.2 mol) of allyl glycidyl ether, 2.6 gm of a carboxylic acid promoter and 0.14 ml of 10% chloroplatinic acid solution. The addition funnel was charged with 122.8 gm (1.0 mol) of trimethoxysilane. The contents of the flask were heated to 90° C. and dropwise addition of trimethoxysilane was begun. The exotherm of the reaction was controlled with an ice bath to maintain the temperature at 90°-95° C. The addition was completed in 25 minutes and temperature was maintained at 90°-95° C. for another hour. Analysis by gas chromatography showed an 86% yield of 3-glycidoxypropyltrimethoxysilane. This example demonstrates a standard preparation of 3-9lycidoxypropyltrimethoxysilane using chloroplatinic acid solution as the catalyst.

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