반응 #1802725

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N-4-nitrophenyl-10-aminodibenzo(A,C)phenazine

→

N-4-aminophenyl-10-aminodibenzo(A,C)phenazine

용매

tetrahydrofuran

반응 조건

후처리

1. 1
   기타the reaction container was purged with nitrogen
2. 2
   workup.ADDITIONThereafter, 4.6 g of 5% Pd/C (hydrous) was added
3. 3
   기타by sufficient purging with nitrogen again
4. 4
   기타This system was purged with hydrogen
5. 5
   기타followed by reaction at room temperature for 10 hours
6. 6
   기타After completion of the reaction
7. 7
   여과the system was filtered
8. 8
   여과the resulting filtration residue
9. 9
   세척was further washed with tetrahydrofuran
10. 10
    기타purified with a column
11. 11
    기타to obtain the intended product

실험 절차

4.5 g (10.8 mmol) of N-4-nitrophenyl-10-aminodibenzo(A,C)phenazine was dissolved in 200 ml of tetrahydrofuran, and the reaction container was purged with nitrogen. Thereafter, 4.6 g of 5% Pd/C (hydrous) was added, followed by sufficient purging with nitrogen again. This system was purged with hydrogen, followed by reaction at room temperature for 10 hours. After completion of the reaction, the system was filtered, and the resulting filtration residue was further washed with tetrahydrofuran and purified with a column to obtain the intended product.

출처