반응 #1797501

ord-984e2a73d7d14cc7b3a454edf29d3d16

반응 방정식

COc1ccc(-c2cc(=O)c3c(OC)c(OC)c(OC)c(OC)c3o2)cc1
tangeretin
C=CCc1cc(OC)c2c(c1)OCO2
Myristicin
C=CCc1cc(OC)c2c(c1OC)OCO2
apiole
CC(C)=CCC[C@](C)(O)C1CC=C(C)CC1
bisabolol
CC(C)=CCC/C(C)=C/COc1c2ccoc2cc2oc(=O)ccc12
bergamotin
C=CCc1ccc(OC)c(OC)c1
Methyleugenol

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타Juvocimene was synthesized

실험 절차

Chemicals were purchased from Sigma-Aldrich Chemical Company (St. Louis, Mo.) unless noted. Plant oils were manufactured by Aura Cacia (Weaverville, Calif.). Juvocimene was synthesized as described (Mestres, R. and E. Munoz, 1996, Synthetic Comm., 26:1309-1319). Myristicin, apiole, bergamotin, tangeretin, bisabolol, and cucurbitacin were obtained from Indofine Chemical Company (Somerville, N.J.). Methyleugenol was provided by the Batelle Chemical Company (Columbus, Ohio). Man-made insecticides were purchased from Chem Service (West Chester, Pa.). The precocene-like suicide substrate 3,4-dimethoxyisopentenylphenol was prepared as described Bowers, W. S., et al., 1976, Science, 217:647-648) except that a 3,4-dimethoxylated reactant was used.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07790377B2uspto-grants-2010_09