반응 #1771991

ord-696188d0a22a43afa651f35351c4c027

반응 방정식

CC1(C)C[C@@H](C(=O)O)N(C(=O)OC(C)(C)C)C1
Boc-Pro(4,4-diMe)-OH
O=S(Cl)Cl
thionylchloride
CO
methanol
COC(=O)[C@@H]1CC(C)(C)CN1.Cl
4,4-Dimethylproline Methylester Hydrochloride Salt

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    농축The reaction mixture was concentrated to an amorphous solid (377 mg, 95%)

실험 절차

To a solution of Boc-Pro(4,4-diMe)-OH (0.5 g, 2.06 mmol) in anhydrous methanol (8 ml) was added dropwise thionylchloride (448 g, 6.18 mmol) and the reaction was stirred for six hours at room temperature. The reaction mixture was concentrated to an amorphous solid (377 mg, 95%).

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: USRE043298E1uspto-grants-2012_04