반응 #170525

ord-9d263cc8f5dd4575b47626a5887d6d94

반응 방정식

Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)O)cn1
6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid
COC(=O)[C@@H](N)Cc1ccccc1.Cl
L-phenylalanine methylester hydrochloride
COC(=O)[C@H](Cc1ccccc1)NC(=O)c1ccc(OCc2c(-c3ccccc3)noc2C)nc1
title compound
수율 88.0%
COC(=O)[C@H](Cc1ccccc1)NC(=O)c1ccc(OCc2c(-c3ccccc3)noc2C)nc1
(S)-2-{[6-(5-Methyl-3-phenyl-isoxazol-4-ylmethoxy)-pyridine-3-carbonyl]-amino}-3-phenyl-propionic acid methyl ester
수율 88.0%

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

As described for example 191, 6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid (111 mg, 0.36 mmol) was converted, using L-phenylalanine methylester hydrochloride instead of 2-aminoethyl isopropylether, to the title compound (148 mg, 88%) which was obtained as a white solid. MS: m/e=470.1 [M−H]−.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US08846719B2uspto-grants-2014_09