반응 #1700730

ord-2e7b5d8173444c7da53deafd40610bef

반응 방정식

CC(C)(C)C1CCCCC1O
2-tert-butylcyclohexanol
CC(C)C1CCCCC1O
2-isopropylcyclohexanol
CC1CO1
propyleneoxide
CCC1CO1
1,2-butyleneoxide
CCC(O)COC1CCCCC1C(C)C
1-(2-isopropylcyclohexyloxy)-2-butanol
CC(C)C1CCCCC1O
2-isopropylcyclohexanol

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

The synthesis was carried out in the same manner as described in Example 1, except that 20.0 g (0.141 mol) of 2-isopropylcyclohexanol (cis:trans=6:4) and 10.1 g (0.141 mol) of 1,2-butyleneoxide were used instead of 30.0 g (0.192 mol) of 2-tert-butylcyclohexanol (cis:trans=8:2) and 11.1 g (0.192 mol) of propyleneoxide. 6.5 g of 2-isopropylcyclohexanol and 16.6 g of 1-(2-isopropylcyclohexyloxy)-2-butanol (cis:trans=6:4) were obtained in a 55% yield.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05194423uspto-grants-1993_03