반응 #161892

반응 방정식

acrylonitrile

hexylamine

→

target compound

수율 98.9%

N,N-bis(2-cyanoethyl)hexylamine

수율 98.9%

반응 조건

후처리

1. 1
   온도to cool to room temperature
2. 2
   추출the mixed solution was extracted with 150 ml of ethyl acetate
3. 3
   기타The organic layer was separated from the solution
4. 4
   건조dried over anhydrous magnesium sulfate
5. 5
   workup.DISTILLATIONdistilled off the solvent

실험 절차

20.1 g of acrylonitrile was added dropwise to an aqueous solution (150 ml) of 15.5 g of hexylamine at room temperature over 0.5 hours, and then the mixed solution was stirred at 70° C. for 3 hours. After standing to cool to room temperature, the mixed solution was extracted with 150 ml of ethyl acetate. The organic layer was separated from the solution, dried over anhydrous magnesium sulfate, and distilled off the solvent to obtain 31.4 g of a target compound as a colorless oily product.

출처