반응 #157088

ord-952089f710114625848889319359b2da

용매

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    농축was concentrated in vacuo
  2. 2
    기타azeotroped once with toluene

실험 절차

TFA was added to a solution of 1-(tert-butoxycarbonyl)-3-methylpiperidine-3-carboxylic acid (1 eq) in CH2Cl2 (0.5 M). After stirring for 3 h at it the reaction mixture was concentrated in vacuo and azeotroped once with toluene to give 3-methylpiperidine-3-carboxylic acid (TFA salt). The crude product was used for the next step without further purification.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US08822497B2uspto-grants-2014_09