반응 #1563881

반응 방정식

p-Toluene sulfonic acid

Iodine

m-CPBA

thiophene

→

dithienyliodonium tosylate

수율 11.2%

용매

dichloromethane

반응 조건

후처리

1. 1
   기타The solution was evaporated to dryness

실험 절차

Iodine (862 mg, 3.39 mmol), m-CPBA (1.48 g, 8.62 mmol) and thiophene (1 g. 11.88 mmol) were combined in dry dichloromethane (66 mL). p-Toluene sulfonic acid (2.19 g, 11.56 mmol) was added to the solution at room temperature, and the mixture was stirred for 16 hours at room temperature. The solution was evaporated to dryness, and the resulting crude product was subjected to flash chromatography (5-10% MeOH/CH2Cl2)) to yield dithienyliodonium tosylate (11.2%) as a brown colored sticky mass.

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