반응 #1470461
ord-45b3a100f5c04085a552849f4fcc1e60
반응 방정식
(5-carboxypentyl)triphenylphosphonium bromide
10-bromodecanal
→
6Z-16-bromohexadec-6-enoic acid
수율 65.0%
반응 조건
상세 조건
See reaction.notes.procedure_details.
실험 절차
60 g (0.13 mol) of (5-carboxypentyl)triphenylphosphonium bromide were suspended in 250 ml of tetrahydrofuran. 30 g (0.26 mol) of potassium t-butylate in 20 ml of tetrahydrofuran were then added. Subsequently, 26 g (0/11 mol) of 10-bromodecanal were added. After usual work up 28 g (65%) of crude 6Z-16-bromohexadec-6-enoic acid were obtained having the following characteristics: Z/E=93/7;