반응 #1470425

반응 방정식

1-oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine

diethanolamine

→

title compound

수율 29.9%

1-Oxyl-2,2,6,6-tetramethyl-4-{2-hydroxy-3-[di(2-hydroxyethyl)amino]propoxy}piperidine

수율 29.9%

용매

water

반응 조건

후처리

1. 1
   추출The solution is then extracted with methylene chloride
2. 2
   추출The methylene chloride extract
3. 3
   건조is dried over anhydrous magnesium sulfate
4. 4
   여과filter
5. 5
   농축concentrated
6. 6
   기타The crude reaction product
7. 7
   기타is purified by column chromatography

실험 절차

A solution of 2.28 g (0.01 mol) of 1-oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine and 1.05 g (0.01 mol) of diethanolamine in 25 mL of water is stirred at ambient temperature for 16 hours. The solution is then extracted with methylene chloride. The methylene chloride extract is dried over anhydrous magnesium sulfate, filter and concentrated. The crude reaction product is purified by column chromatography to afford 1.0 g of the title compound as a red oil.

출처