반응 #1435717

반응 방정식

butane

(2-trimethylsiloxy-ethyl)-cyclopentadiene

butyllithium

hexane

→

lithium (2-trimethylsiloxy-ethyl)-cyclopentadienide

수율 82.0%

용매

ether

반응 조건

후처리

1. 1
   workup.ADDITIONThe addition
2. 2
   기타is realised at −78° C
3. 3
   온도It is maintained
4. 4
   기타Then it is dried
5. 5
   세척the resulting solid washed with hexane
6. 6
   기타leaving a powdery white solid

실험 절차

To 7.33 g of (2-trimethylsiloxy-ethyl)-cyclopentadiene in ether, 16 ml of a 2.5 M butyllithium solution in hexane (40 mmol) is added. The addition is realised at −78° C. The immediate formation of a white solid and butane evolution are observed. It is maintained reacting for 3 hours. Then it is dried; the resulting solid washed with hexane, leaving a powdery white solid. (6.19 g, 33 mmol, Yield: 82%).

출처