반응 #1366316
ord-5e69fe56e7e042fd9f6eb6361228f83f
반응 조건
온도
100°CELSIUS
상세 조건
See reaction.notes.procedure_details.
후처리
- 1온도After cooling it
- 2추출extracted
- 3건조The combined organic extracts were dried (MgSO4)
- 4기타evaporated
- 5기타to give a white solid
- 6기타The crude product was recrystallised from diethyl ether
실험 절차
16-Hexadecanolide (5.0 g, 0.02 mol) was added to a mixture of HI (30 g) and acetic acid (20 g). The mixture was heated to 100° C. overnight. After cooling it was poured into a cold sodium thiosulphate solution (150 mL, 10%) and extracted using CH2Cl2. The combined organic extracts were dried (MgSO4) and evaporated to give a white solid. The crude product was recrystallised from diethyl ether. Yield: 4.8 g (64%)