반응 #1286125

ord-16e1f4ff81fe44c38932169ca63998b8

반응 방정식

CC1CC(=O)NC2=C1C=C(N)CC2(C)C
3,4-dihydro-4,8,8-trimethyl-6-amino-2-(1H)-quinolone
O=[N+]([O-])c1ccccc1F
1-fluoro-2-nitrobenzene
O=C([O-])[O-].[Na+].[Na+]
sodium carbonate
→
CC1CC(=O)NC2=C1C=C(Nc1ccccc1[N+](=O)[O-])CC2(C)C
3,4-Dihydro-4,8,8-trimethyl-6-[(N-2-nitrophenyl)-amino]-2-(1H)-quinolone

반응물

CC1CC(=O)NC2=C1C=C(N)CC2(C)C
3,4-dihydro-4,8,8-trimethyl-6-amino-2-(1H)-quinolone
O=[N+]([O-])c1ccccc1F
1-fluoro-2-nitrobenzene
O=C([O-])[O-].[Na+].[Na+]
sodium carbonate

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타205°14 211°

실험 절차

This compound, m.p. 205°14 211°, was prepared similarly to Preparation 20 using 3,4-dihydro-4,8,8-trimethyl-6-amino-2-(1H)-quinolone, 1-fluoro-2-nitrobenzene, and sodium carbonate as starting materials.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US04898872uspto-grants-1990_02