반응 #1244247

반응 방정식

propanoyl chloride

4-Phenylazophenol

triethylamine

→

product

수율 72.0%

Propionic acid 4-phenylazo-phenyl ester

수율 72.0%

용매

ether

ether

반응 조건

후처리

1. 1
   기타reaction
2. 2
   세척The reaction mixture was washed with water
3. 3
   workup.ADDITIONdilute acid and brine
4. 4
   건조dried with magnesium sulfate
5. 5
   기타The solvent was evaporated

실험 절차

4-Phenylazophenol (0.25 g, 1.26 mmoles) was dissolved in ether (5-10 mL) and triethylamine (0.26 mL) was added. Then propanoyl chloride (0.14 g 1.5 mmoles) in ether (1 mL) was added dropwise at room temperature. The mixture was stirred and reaction was rapidly completed. The reaction mixture was washed with water, dilute acid and brine and dried with magnesium sulfate. The solvent was evaporated to give 0.23 g (72%) of product. 1H NMR (CDCl3) δ=1.16 (3H, t, J=7.7), 2.40 (2H, q J=7.7), 7.25 (2H, m), 7.40-7.58 (3H, m), 7.88-8.0 (4H, m) ppm.

출처