반응 #1178395

반응 방정식

4,4′-dihydroxybenzophenone

→

1,1,2,2-tetrakis(4-hydroxyphenyl)ethylene

수율 83.0%

용매

THF

반응 조건

후처리

1. 1
   온도was refluxed for 20 h
2. 2
   여과filtered
3. 3
   기타The filtrates were evaporated
4. 4
   기타the crude product was purified by a silica gel column
5. 5
   기타DHTPE was obtained as slight yellow powder of 83% yield

실험 절차

A suspension of 4,4′-dihydroxybenzophenone (3.0 g, 14.0 mmol), 1 equiv of TiCl4 (1.54 ml, 14.0 mmol), and 2 equiv of Zn dust (1.83 g, 28.0 mmol) in 100 ml of dry THF was refluxed for 20 h. The reaction mixture was cooled to room temperature and filtered. The filtrates were evaporated and the crude product was purified by a silica gel column using ethyl acetate (EA) as eluent. DHTPE was obtained as slight yellow powder of 83% yield.

출처