반응 #1153631

반응 방정식

dichloromethylvinylsilane

dichloromethane

dimethyl sulphide dichloroborane

→

[(dichloromethylsilyl)]ethyldichloroborane dimethyl sulphide

반응 조건

후처리

1. 1
   기타the solvent was removed under reduced pressure

실험 절차

20 ml (24.44 g; 0.173 mol) of dichloromethylvinylsilane were dissolved in 10 ml of dichloromethane and 20 ml (25.1 g; 0.173 mol) of dimethyl sulphide-dichloroborane were added dropwise at 0° C. with constant stirring. After 5 h at 0° C., the reaction mixture was heated to room temperature and, after a further 24 h, the solvent was removed under reduced pressure. The yield of [(dichloromethylsilyl)]ethyldi-chloroborane-dimethyl sulphide was quantitative.

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