반응 #11279

ord-7b9e1cfe9f4f47438fab95b35771d0d9

반응 방정식

CCCCCCCCC1(CCCCCCCC)c2ccccc2-c2ccc(C(=O)O)cc21
9,9-Dioctyl-9H-fluorene-2-carboxylic acid
O=S(Cl)Cl
thionyl chloride
O=S(Cl)Cl
thionyl chloride
→
CCCCCCCCC1(CCCCCCCC)c2ccccc2-c2ccc(C(=O)Cl)cc21
9,9-Dioctyl-9H-fluorene-2-carbonyl Chloride

반응물

CCCCCCCCC1(CCCCCCCC)c2ccccc2-c2ccc(C(=O)O)cc21
9,9-Dioctyl-9H-fluorene-2-carboxylic acid
O=S(Cl)Cl
thionyl chloride
O=S(Cl)Cl
thionyl chloride

시약

없음

반응 조건

상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    workup.DISTILLATIONwas distilled off
  2. 2
    기타the residue material used without further purification

실험 절차

9,9-Dioctyl-9H-fluorene-2-carboxylic acid (32.36 g, 74.5 mmole) was refluxed in thionyl chloride (93 g, 782 mmole) for 8 hrs. Unreacted thionyl chloride was distilled off and the residue material used without further purification.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US07094902B2uspto-grants-2006_08