반응 #1121721

반응 방정식

chlorosulfonic acid

3-methoxyphenyl benzoate

→

4-benzoyloxy-2-methoxybenzenesulfonic acid

수율 15.0%

용매

dichloromethane

dichloromethane

반응 조건

후처리

1. 1
   workup.ADDITIONOnce the addition
2. 2
   workup.WAITthe mixture was left
3. 3
   기타to react for 18 h at room temperature
4. 4
   여과The formed precipitate was filtered

실험 절차

A solution of 0.47 mL (7.01 mmol) of chlorosulfonic acid in 7 mL of dichloromethane was added drop by drop to a solution of 1.6 g (7.01 mmol) of 3-methoxyphenyl benzoate in 12 mL of dichloromethane at 0° C. Once the addition was completed, the mixture was left to react for 18 h at room temperature. The formed precipitate was filtered, giving 300 mg of 4-benzoyloxy-2-methoxybenzenesulfonic acid. Yield 15%.

출처