반응 #1076742

ord-b80a1c54b00442ef9e8d5fa0d4abfda0

반응 방정식

O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ca+2]
calcium nitrate salt
O.O.O=P([O-])([O-])[O-].[Ca+2].[Ca+2]
dicalcium phosphate dihydrate
C1=CC2C(C1)[C@@H]1C=C[C@H]2C1
DCPD
O=P([O-])([O-])OP(=O)([O-])[O-].[Ca+2].[Ca+2]
calcium pyrophosphate
C1=CC2C(C1)[C@@H]1C=C[C@H]2C1
DCPD
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2]
Calcium Phosphate

반응 조건

온도
500°CELSIUS
상세 조건
See reaction.notes.procedure_details.

후처리

  1. 1
    기타as precipitated material (no agitation
  2. 2
    온도Warming of the sample to >25° C.
  3. 3
    기타an exothermic reaction
  4. 4
    기타resulting in the formation of a white, pasty solid
  5. 5
    온도Heat treatment and X-ray diffraction of this solid

실험 절차

Example 1 was repeated with the addition of 10.00 g dicalcium phosphate dihydrate, DCPD, CaHPO4.2H2O (Aldrich Chemical Co., Inc. #30,765-3, CAS #7789-77-7) to the homogeneous solution following endothermic dissolution of the calcium nitrate salt. The DCPD was present both as suspended solids and as precipitated material (no agitation used). Warming of the sample to >25° C. initiated an exothermic reaction as described in Example 1, resulting in the formation of a white, pasty solid. Heat treatment and X-ray diffraction of this solid were conducted as described in Example 1. Following heat treatment in air at 500° C. for 1 hour, XRD indicated the solid to be composed of whitlockite as the primary phase along with calcium pyrophosphate (Ca2P2O7) as the secondary phase.

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US06458162B1uspto-grants-2002_10