반응 #1061949

반응 방정식

chloromethyl octyl carbonate

sodium iodide

→

iodomethyl octyl carbonate

수율 72.6%

용매

acetone

반응 조건

후처리

1. 1
   농축concentrated invacuo
2. 2
   workup.DISSOLUTIONdissolved in dichloromethane (50 ml)
3. 3
   세척This solution was washed with saturated aqueous sodium chloride, aqueous sodium thiosulfate, and saturated aqueous sodium chloride
4. 4
   건조dried (sodium sulfate)
5. 5
   농축concentrated invacuo

실험 절차

To a solution of chloromethyl octyl carbonate (1.14 g, 0.005 mol) in acetone (10 ml) was added sodium iodide (2.3 g, 0.015 mol). The mixture was stirred for 3 hours, concentrated invacuo, and dissolved in dichloromethane (50 ml). This solution was washed with saturated aqueous sodium chloride, aqueous sodium thiosulfate, and saturated aqueous sodium chloride, dried (sodium sulfate) and concentrated invacuo to yield iodomethyl octyl carbonate (1.14 g).

출처