반응 #10579

반응 방정식

disodium bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate

→

Disodium bicyclo[2.2.1]heptane-2,3-dicarboxylate

용매

water

반응 조건

후처리

1. 1
   여과The activated carbon was filtered out
2. 2
   기타Water is removed in vacuo at 75° C
3. 3
   기타The resulting product was dried
4. 4
   기타milled (m.p >300° C.)

실험 절차

To a solution of disodium bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate (10.0 g, from example 3) in water (100 g) was added 0.5 g palladium on activated carbon (5 wt %). The mixture was transferred into a Parr reactor and was subjected to hydrogenation (50 psi, room temperature) for 8 hours. The activated carbon was filtered out. Water is removed in vacuo at 75° C. The resulting product was dried and milled (m.p >300° C.).

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