반응 #1033

ord-3730779ac7234e61924027d44b783970

반응 조건

상세 조건
See reaction.notes.procedure_details.

실험 절차

A one pot reaction of 1-chloro-1,2-dibromotrifluoroethane (VI) with ethyl vinyl ether in the presence of sodium hydrosulfite/sodium bicarbonate followed by oxidation of the intermediate, 4-bromo-3-chloro-3,4,4-trifluorobutanal (VII), without isolaton, with sodium chlorite/hydrogen peroxide to give 4-bromo-3-chloro-3,4,4-trifiuorobutanoic acid (VIII) in overall unexpected yields;

출처

DOI: 10.6084/m9.figshare.5104873.v1특허: US05723470uspto-grants-1998_03