反応 #987821

反応方程式

propylene glycol methyl ether acetate

methacrylate

2-hydroxyethyl methacrylate

t-butylacrylate

acrylic acid

AIBN

→

methacrylate 2-hydroxyethyl methacrylate t-butylacrylate acrylic acid

収率 88.0%

反応条件

後処理

1. 1
   その他The prepared solution was reacted at 66° C. for 8 hours
2. 2
   その他After the reaction
3. 3
   その他the resulting mixture was precipitated in ethyl ether
4. 4
   ろ過filtered
5. 5
   その他dried under vacuum condition

実験手順

To 50 g of propylene glycol methyl ether acetate (PGMEA) were added 5 g of 9-anthracenemethyl methacrylate, 1 g of 2-hydroxyethyl methacrylate, 3 g of t-butylacrylate, 1 g of acrylic acid and 0.4 g of AIBN. The prepared solution was reacted at 66° C. for 8 hours. After the reaction, the resulting mixture was precipitated in ethyl ether, filtered, and dried under vacuum condition, thereby obtaining poly(9-anthracenemethyl methacrylate/2-hydroxyethyl methacrylate/t-butylacrylate/acrylic acid) having a molecular weight of 12,500 (yield: 88%) (see the NMR spectrum of FIG. 1).

出典