反応 #955948

反応方程式

9-methylphenanthrene

NBS

→

product

収率 89.7%

9-(bromomethyl)phenanthrene

収率 89.7%

溶媒

benzene

反応条件

後処理

1. 1
   温度was refluxed for 5 h
2. 2
   その他the succinimide precipitated
3. 3
   その他was removed by filtration
4. 4
   洗浄The filtrate was washed by 15% NaOH
5. 5
   乾燥dried over MgSO4
6. 6
   濃縮concentrated

実験手順

A mixture of 9-methylphenanthrene (14.2 g, 74 mmol), benzoyl peroxide (40 mg, 0.16 mmol) and NBS (13.3 g, 74.6 mmol) in 210 mL of benzene was refluxed for 5 h. The reaction mixture was cooled to 0° C. and the succinimide precipitated was removed by filtration. The filtrate was washed by 15% NaOH, dried over MgSO4 and concentrated to yield 18 g of product which was used for the next step without further purification.

出典