反応 #955946

反応方程式

Triphenyleno[1,12-bcd]thiophene

Br2

→

7-bromotriphenyleno[1,12-bcd]thiophene

溶媒

chloroform

反応条件

後処理

1. 1
   ろ過the mixture was filtered through a Celite plug
2. 2
   洗浄washed by CH2Cl2
3. 3
   濃縮The combined filtrate was concentrated

実験手順

Triphenyleno[1,12-bcd]thiophene (1.5 g, 5.8 mmol) was dissolved in 100 mL of chloroform. Br2 was slowly added into the reaction solution. After the reaction was stirred at room temperature for 3 days, the mixture was filtered through a Celite plug and washed by CH2Cl2. The combined filtrate was concentrated to get 2.2 g of 7-bromotriphenyleno[1,12-bcd]thiophene which was used for next step without further purification.

出典