反応 #955905

反応方程式

3-(1′-hydroxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene

acryl chloride

→

3-(1′-acryloyloxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene

収率 92.2%

溶媒

pyridine

反応条件

後処理

1. 1
   その他controlled at 0° C.
2. 2
   workup.DISSOLUTIONdissolved
3. 3
   その他the reaction
4. 4
   その他resulting solution
5. 5
   その他was purified via silica gel chromatography (mix solvent of hexane and ethyl acetate)

実験手順

Subsequently, into pyridine controlled at 0° C., dissolved was 4.0 g of 3-(1′-hydroxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene and added 0.50 g of acryl chloride for 30 minutes, followed by stirring 1 hour at room temperature. After finishing the reaction, resulting solution was purified via silica gel chromatography (mix solvent of hexane and ethyl acetate) to obtain 3.9 g of 3-(1′-acryloyloxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene (yield: 92%).

出典