反応 #95320

反応方程式

hydrogen peroxide

tetrachloroacetone

cyclooctene

chloroform

→

cyclooctene oxide

収率 83.0%

溶媒

water

反応条件

後処理

1. 1
   その他Water was removed continuously as it
2. 2
   その他was formed, over a period of 4 hours
3. 3
   温度of heating
4. 4
   その他The organic phase was then separated from the aqueous phase

実験手順

There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis there was obtained an 83% yield of cyclooctene oxide.

出典