反応 #95245

ord-bcf19da25ebc403ebedb533e1153cc41

反応方程式

CCC(CCCCCC1=CCCC1=O)(C(=O)O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]
2-(6,6-dicarboxyoctyl)-2-cyclopentenone methoxime
→
CCC(CCCCCC1=CCCC1=O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]
2-(6-carboxyoctyl)-2-cyclopentenone methoxime

反応物

CCC(CCCCCC1=CCCC1=O)(C(=O)O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]
2-(6,6-dicarboxyoctyl)-2-cyclopentenone methoxime

試薬

なし

溶媒

Cc1ccccc1C
xylene

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    温度at reflux for 18 hours
  2. 2
    その他gives a yellow oil

実験手順

In the manner described in Example 21, treatment of 2-(6,6-dicarboxyoctyl)-2-cyclopentenone methoxime (Example 28) with xylene at reflux for 18 hours gives a yellow oil.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04343949uspto-grants-1982_08