反応 #94251

反応方程式

n-butyl alcohol

pyridine

1,3-dimethyl-3-(t-butylperoxy)butyl chloroformate

→

1,3-Dimethyl-3-(t-butylperoxy)butyl n-butyl carbonate

溶媒

diethyl ether

反応条件

後処理

1. 1
   workup.ADDITIONwas added a solution of 27.0 g
2. 2
   workup.ADDITIONThe reaction temperature was controlled at 15°±1° C during the addition

実験手順

To a solution of 8.1 g. (0.11 mole) of n-butyl alcohol and 7.9 g. (0.1 mole) of pyridine in diethyl ether cooled to 10°±1° C was added a solution of 27.0 g. (0.1 mole) 1,3-dimethyl-3-(t-butylperoxy)butyl chloroformate. The reaction temperature was controlled at 15°±1° C during the addition.

出典