反応 #850

反応方程式

4,4'-Diaminobenzanilide

phenylisothiocyanate

→

colorless crystal

収率 72.3%

4,4'-di(phenylthiocarbamoylamino)benzanilide

収率 72.3%

溶媒

acetone

反応条件

後処理

1. 1
   温度After cooling
2. 2
   ろ過the reaction mixture was filtered
3. 3
   洗浄washed with acetone/n-hexane

実験手順

4,4'-Diaminobenzanilide (0.658 g, 2.5 mM) was dissolved in 20 ml of acetone, and 2 equivalents of phenylisothiocyanate (0.676 g, 5 mM) was added. The mixture was stirred at 55° C. for 10 minutes. After cooling, the reaction mixture was filtered, and washed with acetone/n-hexane to obtain 0.90 g (72.3% yield) of a colorless crystal of compound A-15.

出典