反応 #82888

反応方程式

α-methyl-styrene

α-methylstyrene

butadiene

water

→

α-methyl styrene butadiene

溶媒

hexane

hexane

反応条件

後処理

1. 1
   その他equipped with an air-driven stirrer
2. 2
   その他The reactor has been previously conditioned for anionic polymerization (purged with dry nitrogen)
3. 3
   workup.ADDITIONwere added

実験手順

The copolymerization of α-methylstyrene and butadiene was carried out in a one-gallon batch reactor equipped with an air-driven stirrer, nitrogen lines, water-cooled coils, a rupture and dump tank as well as a solenoid controller to protect against temperature surges. The reactor has been previously conditioned for anionic polymerization (purged with dry nitrogen). To this reactor was added 38.5 ml of 0.909 g/ml α-methyl-styrene solution in hexane and 800 grams of 17.5 percent Bd solution in hexane were added to give a 10/90 ratio of α-methyl styrene/butadiene. The initial concentration was determined by GC analysis to be 18.3 percent solids. The reactor contents were adjusted to the reaction temperature of 65° C. and were equilibrated.

出典