反応 #81382

ord-36461e8532db42809efa1d16c749e9dc

反応方程式

O=S(=O)=O.c1ccncc1
sulfur trioxide pyridine
OC[C@H]1O[C@@](CO)(O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@@H]1O
sucrose
→
O=S(=O)(O)OC[C@H]1O[C@@](COS(=O)(=O)O)(O[C@H]2O[C@H](COS(=O)(=O)O)[C@@H](OS(=O)(=O)O)[C@H](OS(=O)(=O)O)[C@H]2OS(=O)(=O)O)[C@@H](OS(=O)(=O)O)[C@@H]1OS(=O)(=O)O
Sucrose octasulfate

反応物

O=S(=O)=O.c1ccncc1
sulfur trioxide pyridine
OC[C@H]1O[C@@](CO)(O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)[C@@H](O)[C@@H]1O
sucrose

試薬

なし

溶媒

O
water

反応条件

温度
65°CELSIUS
詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他the substance was separated as a thick
  2. 2
    その他When the reaction was terminated
  3. 3
    その他the pyridine phase was decanted
  4. 4
    workup.DISSOLUTIONthe oily phase was dissolved in 600 ml of ion-exchanged water

実験手順

254.7 g (1.6 mol) of sulfur trioxide pyridine were slurried in 1300 ml of water-free pyridine. With stirring, 68.5 g (0.2 mol) of sucrose were added. The reaction mixture was heated to 65° C. and kept at this temperature for 240 minutes. As the reaction proceeded, the substance was separated as a thick flowing oil. When the reaction was terminated, the agitator was stopped, the pyridine phase was decanted, and the oily phase was dissolved in 600 ml of ion-exchanged water.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05618798uspto-grants-1997_04