反応 #80962

反応方程式

3,3,3-trifluoro-1-propene

cyclopentyldiethoxysilane

→

3,3,3-trifluoropropylcyclopentyldiethoxysilane

収率 77.0%

溶媒

p-xylene

反応条件

実験手順

In analogy to Example 3, a mixture of 3 g of p-xylene, 5.3 g (0.055 mol) of 3,3,3-trifluoro-1-propene and 9.4 g (0.5 mol) of cyclopentyldiethoxysilane was reacted in the presence of 0.1 mg of iridium(III) chloride hydrate, after a mixing time of 70 minutes, at 83° C. over 180 minutes. Analysis by gas chromatography gave a product yield of 77% of 3,3,3-trifluoropropylcyclopentyldiethoxysilane.

出典