反応 #80961

反応方程式

allyl chloride

triethoxysilane

→

3-chloropropyltriethoxysilane

収率 61.0%

溶媒

p-xylene

反応条件

後処理

1. 1
   workup.ADDITIONa relatively long mixing

実験手順

In analogy to Example 3, a homogeneous reaction solution of 4 g of p-xylene, 3.8 g (0.05 mol) of allyl chloride (instead of 4.2 g corresponding to 0.055 mol), 8.2 g (0.05 mol) of triethoxysilane and 0.16 mg (10-3 mol %) of chloro-(1,5-cyclooctadiene)iridium(I) dimer were reacted without a relatively long mixing or storage time. Analysis by gas chromatography gave a product yield of only 61% of 3-chloropropyltriethoxysilane.

出典